Needing to win the remaining limited overs fixtures to reclaim the Ashes, the Southern Stars compiled 7-266 after Nicole Bolton (124) became the first Australian woman to strike a century on debut.
Commonwealth Bank VicSpirit run-machine Jess Cameron added 44, while state teammate Julie Hunter claimed 1-39 as England was dismissed for 240 in the 47th over.
To see a full scorecard, click here.
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